OK. Firstly, when you got your new PS3 you should have been able to login with an existing PSN account without needing to make a new one - although that's kind of irrelevant now unless you want to simply change your PSN login details on your PS3 to your original PSN account.
If you check out the EA Football World sticky that I made it will tell you how you can set your default persona on EA Football World, try following the instructions and see if your new PSN persona is available in the persona drop-down list. If it is then set that as your default persona. If it isn't then I would suggest contacting EA Support.
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